Effective Removal of Heavy Metal Ions Using Glycerol and Starch Xanthate

Aliyu Mohammed; Johan Hendriks

doi:10.18596/jotcsa.311942

Araştırma Makalesi

Effective Removal of Heavy Metal Ions Using Glycerol and Starch Xanthate

Yıl 2017, Cilt: 4 Sayı: 3, 1031 - 1044, 29.09.2017

Aliyu Mohammed Johan Hendriks

https://doi.org/10.18596/jotcsa.311942

Cited By: 4

Öz

Glycerol and insoluble
starch xanthates were synthesised and effectively used in the removal of Pb, Cd
and Cu from aqueous solutions. The insoluble metal complex formed between the
sulphur atoms in the xanthates and the heavy metals were easily separated.
Lower dosage of glycerol xanthate was required in each case, with the optimum
molar ratio (M²⁺/GX) of 2. Moreover, the use of glycerol xanthate
required no pH adjustments to give a 100 % heavy metal removal within the range
of the detection limit. As for the ISX, there was a remarkable metal scavenging
activity when the ISX contained high amount of Sulphur per molecule (10.12% S)
and when the pH was adjusted to 6. Butyl xanthate was also synthesised to make
a good comparison with the glycerol and insoluble starch xanthate. The
xanthates from these two sustainable materials (Starch and glycerol) are proven
to be more effective in metal scavenging activity. FTIR and CHNS elemental
analyses were used to prove the evidence of xanthation, in addition, ¹³C
NMR was used to characterise the glycerol xanthate.

Anahtar Kelimeler

Glycerol, Heavy metals, Starch, Sulphur

Kaynakça

1. Brostow W, Pal S, Sing R. P., A Model of Flocculation. Materials Letters, 2007;February:61(22):4381–4.
2. Guo L., S. Zhang S., Ben-Zhi Ju B., Yang J., Quan X., Removal of Pb(II) from Aqueous Solution by Cross-linked Starch Phosphate Carbamate. Journal of Polymer Research. 2006 September;13(3):213–7.
3. Chaudhari S., Tare V., Heavy Metal–Soluble Starch Xanthate Interactions in Aqueous Environments. Journal of Applied Polymer Science. 1999 Feb 22;71(8):1325–32.
4. Patterson J. W., Effect of carbonate ion on precipitation treatment of cadmium, copper and lead. Proceeding 36th annual industrial waste conference, Purdue University, West Lafayette, Indiana 1981;579-602
5. Chang YK., Shih PH., Chiang LC., Chen TC., Lu HC., Chang JE., Removal of heavy metal by insoluble starch xanthate. Environmental Informatics Archive. 2007;5:684-9.
6. Wing R.E., Doane W. M., Russel C. R., Insoluble starch xanthate: Use in heavy metal removal. Journal of Applied Polymer Science. 1975 Mar;19(3):847–54.
7. Dao-ling X., Yue-hua H., Wen-qin Q., Ming-fei H., Synthesis of glycerine-xanthate and its depressing mechanism in separation of marmatite from arsenopyrite. Journal of Central South University of Technology. 2006 Dec;13(6):678–82.
8. Mohamed A. A, Kani I., Ramirez A. O., Fackler J. P., Synthesis, Characterization, and Luminescent Properties of Dinuclear Gold(I) Xanthate Complexes: X-ray Structure of [Au2( nBu-xanthate)2. Inorganic Chemistry. 2004 Jun;43(13):3833–9.
9. Gorgulu A. O., Celikkan H., Arslana M., The Synthesis, Characterization and Electrochemical Behaviour of Transition Metal Complexes Containing Nitrogen Heterocyclic Sulphur Donor Ligand. Acta Chimica Slovenica. 2009 Jul;56:334-9.
10. Tan R., Datong Song D., C−H and C−S Activations of Quinoline-Functionalized Thiophenes by Platinum Complexes. Organometallics. 2011 Mar; 30:1637–45.
11. Mostafa, KM., Samarkandy M., El-Sanabary AA. Graft Copolymers and their Application in Waste Water Treatment. Journal of Applied Polymer Science. 2009 Nov;112:2838-46.
12. Dharmadi Y., Murarka A, Gonzalez R., Anaerobic Fermentation of Glycerol by E. Coli. Biotechnology and Bioengineering. 2006 Aug;94:821-9.

Yıl 2017, Cilt: 4 Sayı: 3, 1031 - 1044, 29.09.2017

Aliyu Mohammed Johan Hendriks

https://doi.org/10.18596/jotcsa.311942

Cited By: 4

Öz

Kaynakça

1. Brostow W, Pal S, Sing R. P., A Model of Flocculation. Materials Letters, 2007;February:61(22):4381–4.
2. Guo L., S. Zhang S., Ben-Zhi Ju B., Yang J., Quan X., Removal of Pb(II) from Aqueous Solution by Cross-linked Starch Phosphate Carbamate. Journal of Polymer Research. 2006 September;13(3):213–7.
3. Chaudhari S., Tare V., Heavy Metal–Soluble Starch Xanthate Interactions in Aqueous Environments. Journal of Applied Polymer Science. 1999 Feb 22;71(8):1325–32.
4. Patterson J. W., Effect of carbonate ion on precipitation treatment of cadmium, copper and lead. Proceeding 36th annual industrial waste conference, Purdue University, West Lafayette, Indiana 1981;579-602
5. Chang YK., Shih PH., Chiang LC., Chen TC., Lu HC., Chang JE., Removal of heavy metal by insoluble starch xanthate. Environmental Informatics Archive. 2007;5:684-9.
6. Wing R.E., Doane W. M., Russel C. R., Insoluble starch xanthate: Use in heavy metal removal. Journal of Applied Polymer Science. 1975 Mar;19(3):847–54.
7. Dao-ling X., Yue-hua H., Wen-qin Q., Ming-fei H., Synthesis of glycerine-xanthate and its depressing mechanism in separation of marmatite from arsenopyrite. Journal of Central South University of Technology. 2006 Dec;13(6):678–82.
8. Mohamed A. A, Kani I., Ramirez A. O., Fackler J. P., Synthesis, Characterization, and Luminescent Properties of Dinuclear Gold(I) Xanthate Complexes: X-ray Structure of [Au2( nBu-xanthate)2. Inorganic Chemistry. 2004 Jun;43(13):3833–9.
9. Gorgulu A. O., Celikkan H., Arslana M., The Synthesis, Characterization and Electrochemical Behaviour of Transition Metal Complexes Containing Nitrogen Heterocyclic Sulphur Donor Ligand. Acta Chimica Slovenica. 2009 Jul;56:334-9.
10. Tan R., Datong Song D., C−H and C−S Activations of Quinoline-Functionalized Thiophenes by Platinum Complexes. Organometallics. 2011 Mar; 30:1637–45.
11. Mostafa, KM., Samarkandy M., El-Sanabary AA. Graft Copolymers and their Application in Waste Water Treatment. Journal of Applied Polymer Science. 2009 Nov;112:2838-46.
12. Dharmadi Y., Murarka A, Gonzalez R., Anaerobic Fermentation of Glycerol by E. Coli. Biotechnology and Bioengineering. 2006 Aug;94:821-9.

Toplam 12 adet kaynakça vardır.

Ayrıntılar

Konular	Mühendislik, Kimya Mühendisliği
Bölüm	Makaleler
Yazarlar	Aliyu Mohammed Johan Hendriks Bu kişi benim
Yayımlanma Tarihi	29 Eylül 2017
Gönderilme Tarihi	11 Mayıs 2017
Kabul Tarihi	29 Eylül 2017
Yayımlandığı Sayı	Yıl 2017 Cilt: 4 Sayı: 3

Kaynak Göster

Vancouver	Mohammed A, Hendriks J. Effective Removal of Heavy Metal Ions Using Glycerol and Starch Xanthate. JOTCSA. 2017;4(3):1031-44.

Cited By

Theoretical studies of Zn2+ complexes with alkyl xanthate ligands: a thermochemical, electronic energy decomposition, and natural bond orbital analysis

Journal of the Turkish Chemical Society Section A: Chemistry

Effective Removal of Heavy Metal Ions Using Glycerol and Starch Xanthate

Öz

Anahtar Kelimeler

Kaynakça

Öz

Kaynakça

Ayrıntılar

Kaynak Göster

Cited By

Theoretical studies of Zn2+ complexes with alkyl xanthate ligands: a thermochemical, electronic energy decomposition, and natural bond orbital analysis

Journal of Molecular Modeling

https://doi.org/10.1007/s00894-023-05604-6

Focus on the removal of lead and cadmium ions from aqueous solutions using starch derivatives: A review

Carbohydrate Polymers

https://doi.org/10.1016/j.carbpol.2022.119463

Colour Removal from Biologically Treated Textile Dyeing Wastewater with Natural and Novel Pre-Hydrolysed Coagulants

Journal of the Turkish Chemical Society, Section A: Chemistry

G. Yıldız Töre

https://doi.org/10.18596/jotcsa.370752

Cross-linked-substituted (esterified/etherified) starch derivatives as aqueous heavy metal ion adsorbent: a review

Water Science and Technology

Ayodele Akinterinwa

https://doi.org/10.2166/wst.2020.332